世界首套特高压“可控自恢复消能装置”建成投产

远讲场景语音不仅能听懂命令，世界首套还能连贯地执行命令。

金属纳米团簇具有光学、特高投产催化、手性、磁性、电化学等性质，下面主要介绍前三类性质。尽管已经有许多基于质谱和其他表征技术的原子级精确金属纳米团簇的报道，控自但只有一些可用于单晶结构的检测。

可以说，恢复这篇综述介绍范围相当广泛，值得细细研究。由于手性是一种几何性质，装置文中还讨论了其量化的方案，以及这种几何测量与光学反应的相关性，如从量子力学方法计算的圆二色光谱。在过去的30年中，建成手性也在纳米级研究，是纳米科学的热门研究课题。

如果我们想超越对特定情况的研究，世界首套还需要努力建立一个统一的理论，世界首套包括解释金属催化中的所有情况，无论是基于均相还是非均相化学，光化学，电化学或光电化学催化剂。特高投产左手和右手对映体分别以品红色和黄色着色[1]。

七、控自参考文献（标红的为文章中提到的综述）[1] Yan,N.;Xia,N.;Liao,L.;Zhu,M.;Jin,F.;Jin,R.;Wu,Z.Unravelingthelong-pursuedAu144 structurebyx-raycrystallography. Sci.Adv.2018,4,DOI:10.1126/sciadv.aat7259.[2]Jin,R.;Zeng,C.;Zhou,M.;Chen,Y.AtomicallyPreciseColloidalMetalNanoclustersandNanoparticles:FundamentalsandOpportunities.Chem.Rev. 2016,116,10346-10413.[3]Yao,Q.;Chen,T.;Yuan,X.;Xie,J.TowardTotalSynthesisofThiolate-ProtectedMetalNanoclusters.Acc.Chem.Res.2018, 51,1338-1348.[4]Luo,Z.;Nachammai,V.;Zhang,B.;Yan,N.;Leong,D.T.;Jiang,D.-e.;Xie,J.TowardUnderstandingtheGrowthMechanism:TracingAllStableIntermediateSpeciesfromReductionofAu(I)-ThiolateComplexestoEvolutionofAu25 Nanoclusters.J.Am.Chem.Soc. 2014,136,10577-10580.[5]Yao,Q.;Yuan,X.;Fung,V.;Yu,Y.;Leong,D.T.;Jiang,D.-e.;Xie,J.UnderstandingSeed-MediatedGrowthofGoldNanoclustersatMolecularLevel.Nat.Commun. 2017,8,927.[6]Wang,S.;Li,Q.;Kang,X.;Zhu,M.CustomizingtheStructure,Composition,andPropertiesofAlloyNanoclustersbyMetalExchange.Acc.Chem.Res.2018, 51, 2784-2792.[7]Yao,Q.;Feng,Y.;Fung,V.;Yu,Y.;Jiang,D.-e.;Yang,J.;Xie,J.PreciseControlofAlloyingSitesofBimetallicNanoclustersviaSurfaceMotifExchangeReaction.Nat.Commun. 2017,8,1555.[8]Chakraborty,I.;Pradeep,T.AtomicallyPreciseClustersofNobleMetals:EmergingLinkbetweenAtomsandNanoparticles.Chem.Rev. 2017,117,8208-8271.[9]Negishi,Y.;Nobusada,K.;Tsukuda,T.Glutathione-ProtectedGoldClustersRevisited:BridgingtheGapbetweenGold(I)ThiolateComplexesandThiolate-ProtectedGoldNanocrystals.J.Am.Chem.Soc.2005,127,5261-5270.[10]Negishi,Y.;Chaki,N.K.;Shichibu,Y.;Whetten,R.L.;Tsukuda,T.OriginofMagicStabilityofThiolatedGoldClusters:ACaseStudyonAu25(SC6H13)18. J.Am.Chem.Soc. 2007,129, 11322-11323.[11]Dass,A.;Stevenson,A.;Dubay,G.R.;Tracy,J.B.;Murray,R.W.NanoparticleMALDI-TOFMassSpectrometrywithoutFragmentation:Au25(SCH2CH2Ph)18 andMixedMonolayerAu25(SCH2CH2Ph)18-x(L)x. J.Am.Chem.Soc. 2008,130,5940-5946.[12] Chen,S.;Wang,S.;Zhong,J.;Song,Y.;Zhang,J.;Sheng,H.;Pei,Y.;Zhu,M.TheStructureandOpticalPropertiesofthe[Au18(SR)14]Nanocluster. Angew.Chem.,Int.Ed.2015,54,3145-3149.[13] Zeng,C.;Liu,C.;Chen,Y.;Rosi,N.L.;Jin,R.Gold-ThiolateRingasaProtectingMotifintheAu20(SR)16 NanoclusterandImplications.J.Am.Chem.Soc.2014,136,11922-11925.[14] Das,A.;Li,T.;Nobusada,K.;Zeng,C.;Rosi,N.L.;Jin,R.Nonsuperatomic[Au23(SC6H11)16]- NanoclusterFeaturingBipyramidalAu15 KernelandTrimericAu3(SR)4 Motif. J.Am.Chem.Soc.2013,135,18264-18267.[15]Crasto,D.;Barcaro,G.;Stener,M.;Sementa,L.;Fortunelli,A.;Dass,A.Au24(SAdm)16 Nanomolecules:X-rayCrystalStructure,TheoreticalAnalysis,AdaptabilityofAdamantaneLigandstoFormAu23(SAdm)16 andAu25(SAdm)16,andItsRelationtoAu25(SR)18.J.Am.Chem.Soc. 2014, 136, 14933-14940.[16]Heaven,M.;Dass,A.;White,P.;Holt,K.;Murray,R.CrystalStructureoftheGoldNanoparticle[N(C8H17)4]-[Au25(SCH2CH2Ph)18].J.Am.Chem.Soc.2008,130,3754-3755.[17]Zhu,M.;Aikens,C.M.;Hollander,F.J.;Schatz,G.C.;Jin,R.CorrelatingtheCrystalStructureofAThiol-ProtectedAu25 ClusterandOpticalProperties.J.Am.Chem.Soc.2008, 130,5883-5885.[18]Zeng,C.;Li,T.;Das,A.;Rosi,N.L.;Jin,R.ChiralStructureofThiolate-Protected28-Gold-AtomNanoclusterDeterminedbyX-rayCrystallography.J.Am.Chem.Soc.2013,135,10011-10013.[19]Crasto,D.;Malola,S.;Brosofsky,G.;Dass,A.;Hakkinen,H.̈SingleCrystalXRDStructureandTheoreticalAnalysisoftheChiralAu30S(S-t-Bu)18 Cluster.J.Am.Chem.Soc.2014,136,5000-5005.[20]Zeng,C.;Qian,H.;Li,T.;Li,G.;Rosi,N.L.;Yoon,B.;Barnett,R.N.;Whetten,R.L.;Landman,U.;Jin,R.TotalStructureandElectronicPropertiesoftheGoldNanocrystalAu36(SR)24.Angew.Chem.,Int.Ed. 2012,51,13114-13118.[21]Qian,H.;Eckenhoff,W.T.;Zhu,Y.;Pintauer,T.;Jin,R.TotalStructureDeterminationofThiolate-ProtectedAu38 Nanoparticles. J.Am.Chem.Soc. 2010, 132, 8280-8281.[22]Zeng,C.;Chen,Y.;Liu,C.;Nobusada,K.;Rosi,N.L.;Jin,R.GoldTetrahedraCoilup:Kekule-likeandDoubleHelicalSuper-structures.Sci.Adv.2015,1, e1500425.[23]Zeng,C.;Liu,C.;Chen,Y.;Rosi,N.L.;Jin,R.AtomicStructureofSelf-AssembledMonolayerofThiolatesonaTetragonalAu92 Nanocrystal.J.Am.Chem.Soc.2016,138,8710-8713.[24]Jadzinsky,P.D.;Calero,G.;Ackerson,C.J.;Bushnell,D.A.;Kornberg,R.D.StructureofaThiolMonolayer-ProtectedGoldNanoparticleat1.1ÅResolution.Science2007, 318,430-433.[25]Chen,Y.;Zeng,C.;Liu,C.;Kirschbaum,K.;Gayathri,C.;Gil,R.R.;Rosi,N.L.;Jin,R.CrystalStructureofBarrel-ShapedChiralAu130(p-MBT)50 Nanocluster.J.Am.Chem.Soc.2015,137,10076-10079.[26]Dass,A.;Theivendran,S.;Nimmala,P.R.;Kumara,C.;Jupally,V.R.;Fortunelli,A.;Sementa,L.;Barcaro,G.;Zuo,X.;Noll,B.C.Au133(SPh-tBu)52 Nanomolecules:X-rayCrystallography,Optical,Electrochemical,andTheoreticalAnalysis.J.Am.Chem.Soc. 2015,137,4610-4613.[27]Wu,Z.;Jin,R.StabilityoftheTwoAu-SBindingModesinAu25(SG)18NanoclustersProbedbyNMRandOpticalSpectroscopy.ACSNano2009,3,2036-2042.[28]Cook,A.W.;Hayton,T.W.CaseStudiesinNanoclusterSynthesisandCharacterization:ChallengesandOpportunities.Acc.Chem.Res., 2018, 51,2456-2464.[29] Jin,R.Atomicallyprecisemetalnanoclusters:stablesizesandopticalproperties.Nanoscale,2015,7,1549-1565.[30]Tang,Z.;Xu,B.;Wu,B.;Robinson,D.A.;Bokossa,N.;Wang,G.MonolayerReactionsofProtectedAuNanoclusterswithMonothiolTioproninand2,3-DithiolDimercaptopropanesulfonate.Langmuir,2011,27,2989-2996.[31]Tang,Z.;Ahuja,T.;Wang,S.;Wang,G.NearInfraredLuminescenceofGoldNanoclustersAffectedbytheBondingof1,4-DithiolateDureneandMonothiolatePhenylethanethiolate.Nanoscale,2012,4,4119-4124.[32]Conroy,C.V.;Jiang,J.;Zhang,C.;Ahuja,T.;Tang,Z.;Prickett,C.A.;Yang,J.J.;Wang,G.EnhancingnearIrLuminescenceofThiolateAuNanoclustersbyThermoTreatmentsandHeterogeneousSubcellularDistributions.Nanoscale,2014,6,7416-7423.[33]Negishi,Y.;Iwai,T.;Ide,M.ContinuousModulationofElectronicStructureofStableThiolate-ProtectedAu25 ClusterbyAgDoping.Chem.Commun. 2010,46,4713-4715.[34]Wang,S.;Meng,X.;Das,A.;Li,T.;Song,Y.;Cao,T.;Zhu,X.;Zhu,M.;Jin,R.A200-FoldQuantumYieldBoostinthePhotoluminescenceofSilver-DopedAgxAu25-xNanoclusters:The13thSilverAtomMatters.Angew.Chem.,Int.Ed.2014,53,2376-2380.[35] Goswami,N.;Yao,Q.;Luo,Z.;Li,J.;Chen,T.;Xie,J. LuminescentMetalNanoclusterswithAggregation-InducedEmission. J.Phys.Chem.Lett. 2016,7,962-975.[36] Luo,Z.;Yuan,X.;Yu,Y.;Zhang,Q.;Leong,D.T.;Lee,J.Y.; Xie,J.FromAggregation-InducedEmissionofAu(I)-Thiolate ComplexestoUltrabrightAu(0)@Au(I)-ThiolateCore-ShellNanoclusters.J.Am.Chem.Soc. 2012,134,16662-16670.[37] Ramakrishna,G.;Varnavski,O.;Kim,J.;Lee,D.;Goodson,T. Quantum-SizedGoldClustersasEfficientTwo-PhotonAbsorbers.J. Am.Chem.Soc. 2008,130,5032-5033.[38] Philip,R.;Chantharasupawong,P.;Qian,H.;Jin,R.;Thomas, J.EvolutionofNonlinearOpticalProperties:FromGoldAtomic ClusterstoPlasmonicNanocrystals.NanoLett.2012,12,4661-4667.[39] Knoppe,S.;Vanbel,M.;vanCleuvenbergen,S.;Vanpraet,L.; Bürgi,T.;Verbiest,T.NonlinearOpticalPropertiesofThiolateProtectedGoldClusters.J.Phys.Chem.C2015,119,6221-6226.[40] Knoppe,S.;Hakkinen,H.;Verbiest,T.NonlinearOptical̈ PropertiesofThiolate-ProtectedGoldClusters:ATheoreticalSurvey oftheFirstHyperpolarizabilities. J.Phys.Chem.C 2015,119,27676-27682.[41] Yau,S.H.;Varnavski,O.;Goodson,T.,III.AnUltrafastLook atAuNanoclusters. Acc.Chem.Res. 2013,46,1506-1516.[42] Zhou,M.;Vdovic,S.;Long,S.R.;Zhu,M.Z.;Yan,L.Y.;Wang,Y.Y.;Niu,Y.L.;Wang,X.F.;Guo,Q.J.;Jin,R.C.;IntramolecularChargeTransferandSolvationDynamicsofThiolateProtectedAu20(SR)16 ClustersStudiedbyUltrafastMeasurement.J. Phys.Chem.A 2013,117,10294-10303.[43] ShangL,DongS,NienhausGU.Ultra-smallfluorescentmetalnanoclusters:Synthesisandbiologicalapplications.NanoToday,2011,6,401-418.[44] Tao, Y.; Li, M.; Ren, J.; Qu,X.Metalnanoclusters:novelprobesfordiagnosticandtherapeuticapplications.Chem.Soc.Rev. 2016,47,8636-8663.[45] Liu, L.; Corma, A.MetalCatalystsforHeterogeneousCatalysis:FromSingleAtomstoNanoclustersandNanoparticles. Chem.Rev. 2018,118,4981-5079. [46] Tang, Q.; Hu, G.; Fung, V.;Jiang,D. InsightsintoInterfaces,Stability,ElectronicProperties,andCatalyticActivitiesofAtomicallyPreciseMetalNanoclustersfromFirstPrinciples.Acc.Chem.Res., 2018, 51,2793-2802.[47]Pelayo,J.Jesús,ValenciaI,García,A.Patricio,etal.Chiralityinbareandligand-protectedmetalnanoclusters.Adv. Phys.,2018,3,965-998.[48] Zhang,X.-D.;Luo,Z.;Chen,J.;Shen,X.;Song,S.;Sun,Y.; Fan,S.;Fan,F.;Leong,D.T.;Xie,J.UltrasmallAu10-12(SG)10-12 NanomoleculesforHighTumorSpecificityandCancerRadiotherapy. Adv.Mater. 2014,26,4565-4568.作者水平有限，控自如有遗漏或者陈述不妥的地方，望指正批评，感激不已。

包括催化氧化、恢复催化加氢、C-C偶联反应、电子转移催化、电催化、光催化，光电化学水分解和光伏等各种催化类型[2]。装置d)SC-NS和SC-MR样品的循环稳定性。

任Adv.Mater.客座编辑，建成Acc.Chem.Res.、Joule、ACSEnergyLett.、Adv.Electron.Mater.国际编委，NanoRes.、Sci.ChinaMater.编委。世界首套作者所提出的策略为使用软碳纳米片实现高能量和高倍率的储能装置提供了重要的参考。

特高投产图5SC-NS系列材料的双离子全电池性能a)软碳/膨胀石墨双离子全电池的工作原理示意图。控自b)SC-NS和SC-MR电极的倍率性能。